Foto dell'editore

PVC Degradation and Stabilization

Wypych, George

Editore: ChemTec Publishing, 2008
ISBN 10: 1895198399 / ISBN 13: 9781895198393
Nuovi / Quantità: 1
Da Book Deals (Lewiston, NY, U.S.A.)
Copie del libro da altre librerie
Mostra tutte le  copie di questo libro
Aggiungere al carrello
Prezzo consigliato:
Prezzo: EUR 527,86
Convertire valuta
Spedizione: EUR 0,00
In U.S.A.
Destinazione, tempi e costi

Lista dei preferiti


Dati bibliografici

Titolo: PVC Degradation and Stabilization

Casa editrice: ChemTec Publishing

Data di pubblicazione: 2008

Condizione libro: New


Brand New, Unread Copy in Perfect Condition. A+ Customer Service! Summary: 1 Chemical Structure of PVC 1.1 Repeat structures and their basic organic chemistry 1.1.1 Bronsted acid source with controllable emission 1.2 Molecular weight and its distribution 1.2.1 Kuhn-Mark-Houwink-Sakurada 1.2.2 Fikentscher K number 1.2.3 Chain length 1.3 Prediction of formation of irregular segments 1.3.1 Ab initio 1.3.2 Monte Carlo 1.4 Irregular segments 1.4.1 Branches 1.4.2 Tertiary chlorine 1.4.3 Unsaturations 1.4.4 Oxygen containing groups Ketochloroallyl groups a- and b-carbonyl groups 1.4.5 Head-to-head structures 1.4.5 Initiator rests 1.4.6 Transfer agent rests 1.4.8 Defects introduced during processing 1.4.9 PVC having increased stability References 2 PVC Manufacture Technology 2.1 Monomer 2.2 Basic Steps of Radical Polymerization 2.2.1 Initiation 2.2.2 Propagation 2.2.3 Termination 2.2.4 Chain transfer to monomer 2.3 Polymerization technology 2.3.1 Suspension 2.3.2 Paste resin manufacturing processes 2.3.3 Bulk 2.3.4 Solution 2.4 Polymerization conditions and PVC properties References 3 PVC Morphology 3.1. Molecular weight of polymer (chain length) 3.2. Configuration and conformation 3.3. Chain folds 3.4. Chain thickness 3.5 Entanglements 3.6 Crystalline structure 3.7 Grain morphology 3.7.1 Stages of morphology development during manufacture Suspension polymerization Paste grades manufacture Bulk polymerization 3.7.2 Effect of morphology on degradation References 4 Principles of Thermal Degradation 4.1 The reasons for polymer instability 4.1.1 Structural defects Branches Tertiary chlorine Unstaturations Oxygen containing groups Head-to-head structures Morphology 4.1.2 Polymerization residue Initiator rests Transfer agent rests Polymerization additives 4.1.3 Metal derivatives Metal chlorides Copper and its oxide 4.1.4 Hydrogen chloride 14 4.1.5 Impurities 4.1.6 Shear 4.1.7 Temperature 4.1.8 Surrounding atmosphere 4.1.9 Additives 4.2 Mechanisms of thermal degradation 4.2.1 Molecular mechanism 4.2.2 Amer-Shapiro mechanism 4.2.3 Six-center concerted mechanism 4.2.4 Activation enthalpy 4.2.5 Radical-chain theory 4.2.6 Ionic 4.2.7 Polaron 4.2.8 Degenerated branching 4.2.9 Transition state theory 4.2.10 Recapitulation 4.3 Kinetics 4.3.1 Initiation 4.3.2 Propagation 4.3.3 Termination 4.4 Results of thermal degradation 4.4.1 Volatiles 4.4.2 Weight loss 4.4.3 Char formation 4.4.4 Ash content 4.4.5 Thermal lifetime 4.4.6 Optical properties Color change Extinction coefficient Absorbance 4.4.7 Molecular weight 4.4.8 Mechanical properties 4.4.9 Electric properties 4.5 Effect of additives 4.5.1 Blend polymers ABS Chlorinated polyethylene, CPE Epoxidized butadiene/styrene block copolym. Codice inventario libreria ABE_book_new_1895198399

Info su libreria e pagamento

Metodi di pagamento

La libreria accetta i seguenti metodi di pagamento:

  • American Express
  • Carte Bleue
  • Mastercard
  • Visa

[Cercare nel catalogo della libreria]

[Tutti i libri della libreria]

[Fare una domanda alla libreria]

Libreria: Book Deals
Indirizzo: Lewiston, NY, U.S.A.

Libreria AbeBooks dal: 7 maggio 2014
Valutazione libreria: 4 stelle

Condizioni di vendita:

We guarantee the condition of every book as it's described on the AbeBooks web
sites. If you're dissatisfied with your purchase (Incorrect Book/Not as
Described/Damaged) or if the order hasn't arrived, you're eligible for a refund
within 30 days of the estimated delivery date. If you've changed your mind
about a book that you've ordered, please use the Ask bookseller a question link
to contact us and we'll respond within 2 business days.

Condizioni di spedizione:

Shipping costs are based on books weighing 2.2 LB, or 1 KG. If your book order is heavy or oversized, we may contact you to let you know extra shipping is required.