Additions to and Substitutions at C-c ?-bonds - Rilegato

Trost, B. M.; Fleming, Ian; Semmelhack, M. F.

Rilegato

ISBN 10: 0080405959 ISBN 13: 9780080405957

Casa editrice: Pergamon Pr, 1992

Riassunto

Volume 4 focuses on additions and the resulting substitutions at carbon-carbon &pgr;-bonds. Part 1 includes processes generally considered as simple polar reactions, reactive electrophiles and nucleophiles adding to alkenes and alkynes. A major topic is Michael-type addition to electron deficient &pgr;-bonds, featured in the first six chapters. In part 2 are collected the four general processes leading to nucleophilic aromatic substitution, including radical chain processes and transition metal activation through to &pgr;-complexation. Metal-activated addition (generally by nucleophiles) to alkenes and polyenes is presented in part 3, including allylic alkylation catalyzed by palladium. The coverage of nonpolar additions in part 4 includes radical additions, organometal addition (Heck reaction), carbene addition, and 1,3-dipolar cycloadditions.

Dettagli dell?edizione

• Editore: Pergamon Pr
• Data di pubblicazione: 1992
• Lingua: Inglese
• ISBN 10: 0080405959
• ISBN 13: 9780080405957
• Rilegatura: Copertina rigida
• Numero edizione: 1
• Contatto del produttore: non disponibile
• Persona responsabile: non disponibile