Elements of Chemical Thermodynamics - Brossura

Nash, Leonard Kollender

Brossura

ISBN 10: 0486446123 ISBN 13: 9780486446127

Casa editrice: Dover Pubns, 2005

Riassunto

This text addresses the use of purely thermal data in calculating the position of equilibrium in a chemical reaction. Its argument highlights the physical content of thermodynamics, as distinct from purely mathematical aspects. Methods are limited to a very few of the most elementary operations of the calculus, all of which are explained in an appendix. Readers need no more than a sound background in high school mathematics and physics, as well as some familiarity with the leading quantitative concepts of an introductory college chemistry course.
An introduction establishes the fundamentals of temperature, heat and work, reversibility, and pressure-volume work. The first principle of thermodynamics is explored in terms of energy, enthalpy, thermochemistry and Hess's Law, heat capacity, Kirchhoff's equations, and adiabatic processes. Considerations of the second principle of thermodynamics encompass the Carnot cycle, the concept of entropy, and evaluation of entropy changes. The consequences of thermodynamic principles are examined in chapters on the free energies, the Clapeyron equation, ideal solutions and colligative properties, and the equilibrium state and equilibrium constant. Numerous problems appear throughout the text, in addition to 30 fully worked illustrative examples.

Su questo libro

Contenuti

1. Introduction Temperature Heat and Work Reversibility Perssure-Volume Work 2. The First Principle of Thermodynamics Energy Enthalpy Thermochemistry and Hess's Law Heat Capacity Kirchhoff's Equations Adiabatic Processes 3. The Second Principle of Thermodynamics Carnot Cycle The Concept of Entropy Evaluation of Entropy Changes 4. Consequences of the Thermodynamic Principles The Free Energies The Clapeyron Equation Ideal Solutions and Colligative Properties Equilibrium State and Equilibrium Constant Appendices Bibliographical Notes Some Operations of the Calculus Problems Thermochemical Data at 298.15° K Index

Product Description

The use of purely thermal data in calculating the position of equilibrium in a chemical reaction is the focus of this text, which highlights the physical content of thermodynamics, as distinct from purely mathematical aspects. Numerous problems and fully worked illustrative examples. 1970 edition.

Dettagli dell?edizione

• Editore: Dover Pubns
• Data di pubblicazione: 2005
• ISBN 10: 0486446123
• ISBN 13: 9780486446127
• Rilegatura: Copertina flessibile
• Lingua: Inglese
• Numero edizione: 2
• Numero di pagine: 184
• Contatto del produttore: non disponibile