Updated and improved, this revised edition of Michel Barsoum's classic text Fundamentals of Ceramics presents readers with an exceptionally clear and comprehensive introduction to ceramic science. Barsoum offers introductory coverage of ceramics, their structures, and properties, with a distinct emphasis on solid state physics and chemistry. Key equations are derived from first principles to ensure a thorough understanding of the concepts involved. The book divides naturally into two parts. Chapters 1 to 9 consider bonding in ceramics and their resultant physical structures, and the electrical, thermal, and other properties that are dependent on bonding type. The second part (Chapters 11 to 16) deals with those factors that are determined by microstructure, such as fracture and fatigue, and thermal, dielectric, magnetic, and optical properties. Linking the two sections is Chapter 10, which describes sintering, grain growth, and the development of microstructure. Fundamentals of Ceramics is ideally suited to senior undergraduate and graduate students of materials science and engineering and related subjects.
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"We have been using this text for our juniors ever since its first publication. While the focus of the text is ceramics, the treatment of the kinetics of materials process is highly understandable and easily applied to other materials systems. It is an excellent introduction to mass transport and phase transformations in materials."
―Lisa C. Klein, Rutgers University
"Updated and improved, this revised edition present readers with an exceptionally clear and comprehensive introduction to ceramic science."
―Materials World, February 2003
INTRODUCTION 
Introduction 
Definition of Ceramics 
Elementary Crystallography 
Ceramic Microstructures 
Traditional Versus Advanced Ceramics 
General Characteristics of Ceramics 
Applications 
The Future 
BONDING IN CERAMICS 
Introduction 
Structure of Atoms 
Ionic versus Covalent Bonding 
Ionic Bonding 
Ionically Bonded Solids 
Covalent Bond Formation 
Covalently Bonded Solids 
Band Theory of Solids 
Summary 
Appendix 2A: Kinetic Energy of Free Electrons 
STRUCTURE OF CERAMICS 
Introduction 
Ceramic Structures 
Binary Ionic Compounds 
Composite Crystal Structures 
Structure of Covalent Ceramics 
Structure of Silicates 
Lattice Parameters and Density 
Summary 
Appendix 3A: Ionic Radii 
EFFECT OF CHEMICAL FORCES ON PHYSICAL PROPERTIES 
Introduction 
Melting Points 
Thermal Expansion 
Young's Modulus and the Strength of Perfect Solids 
Surface Energy 
Summary 
THERMODYNAMIC AND KINETIC CONSIDERATIONS 
Introduction 
Free Energy 
Chemical Equilibrium and the Mass Action Expression 
Chemical Stability Domains 
Electrochemical Potentials 
Charged Interfaces, Double Layers, and Debye Lengths 
Gibbs-Duhem Relation for Binary Oxides 
Kinetic Considerations 
Summary 
Appendix 5A: Derivation of Eq. (5.27) 
DEFECTS IN CERAMICS 
Introduction 
Point Defects 
Linear Defects 
Planar Defects 
Summary 
DIFFUSION AND ELECTRICAL CONDUCTIVITY 
Introduction 
Diffusion 
Electrical Conductivity 
Ambipolar Diffusion 
Relationships between Self-, Tracer, Chemical, Ambipolar, and Defect Diffusion Coefficients 
Summary 
Appendix 7A: Relationship between Fick's First Law and Eq. (7.30) 
Appendix 7B: Effective Mass and Density of States 
Appendix 7C: Derivation of Eq. (7.79) 
Appendix 7D: Derivation of Eq. (7.92) 
PHASE EQUILIBRIA 
Introduction 
Phase Rule 
One-Component Systems 
Binary Systems 
Ternary Systems 
Free-Energy Composition and Temperature Diagrams 
Summary 
FORMATION, STRUCTURE, AND PROPERTIES OF GLASSES 
Introduction 
Glass Formation 
Glass Structure 
Glass Properties 
Glass-Ceramics 
Summary 
Appendix 9A: Derivation of Eq. (9.7) 
SINTERING AND GRAIN GROWTH 
Introduction 
Solid-State Sintering 
Liquid-Phase Sintering 
Hot Pressing and Hot Isostatic Pressing 
Summary 
Appendix 10A: Derivation of the Gibbs-Thompson Equation 
Appendix 10B: Radii of Curvature 
Appendix 10C: Derivation of Eq. (10.20) 
Appendix 10D: Derivation of Eq. (10.22) 
MECHANICAL PROPERTIES: FAST FRACTURE 
Introduction 
Fracture Toughness 
Strength of Ceramics 
Toughening Mechanisms 
Designing with Ceramics 
Summary 
CREEP, SUBCRITICAL CRACK GROWTH, AND FATIGUE 
Introduction 
Creep 
Subcritical Crack Growth 
Fatigue of Ceramics 
Lifetime Predictions 
Summary 
Appendix 12A: Derivation of Eq. (12.24) 
THERMAL PROPERTIES 
Introduction 
Thermal Stresses 
Thermal Shock 
Spontaneous Microcracking of Ceramics 
Thermal Tempering of Glass 
Thermal Conductivity 
Summary 
DIELECTRIC PROPERTIES 
Introduction 
Basic Theory 
Equivalent Circuit Description of Linear Dielectrics 
Polarization Mechanisms 
Dielectric Loss 
Dielectric Breakdown 
Capacitors and Insulators 
Summary 
Appendix 14A: Local Electric Field 
MAGNETIC AND NONLINEAR DIELECTRIC PROPERTIES 
Introduction 
Basic Theory 
Microscopic Theory 
Para-, Ferro-, Antiferro-, and Ferrimagnetism 
Magnetic Domains and the Hysteresis Curve 
Magnetic Ceramics and their Applications 
Piezo- and Ferroelectric Ceramics 
Summary 
Appendix 15A: Orbital Magnetic Quantum Number 
OPTICAL PROPERTIES 
Introduction 
Basic Principles 
Absorption and Transmission 
Scattering and Opacity 
Fiber Optics and Optical Communication 
Summary 
Appendix 16A: Coherence 
Appendix 16B: Assumptions Made in Deriving Eq. (16.24) 
INDEX 
*Each chapter contains Problems and Additional Reading.
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Da: Burton Lysecki Books, ABAC/ILAB, Winnipeg, MB, Canada
[0-7503-0902-4] 2003. (Trade paperback) Fine. 603pp. Illustrations, tables, formulas, references, index. Publisher series: Series in Materials Science and Engineering. (Science, Ceramics, Science). Codice articolo 159951
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Da: Studibuch, Stuttgart, Germania
hardcover. Condizione: Gut. 624 Seiten; 9780750309028.3 Gewicht in Gramm: 2. Codice articolo 965383
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