Sinossi
Considering the high level of our knowledge concerning covalent bond formation in the organic chemistry of molecules, our understanding of the principles involved in organic solid design is almost in its infancy. While chemists today are able to synthesize organic molecules of very high complexity using sophisticated methods of preparation, they lack general approaches enabling them to reliably predict organic crystalline or solid structures from molecular descriptors - no matter how simple they are. On the other hand, nearly all the organic matter surrounding us is not in the single-molecule state but aggregated and condensed to form liquid or solid molecular assemblages and structural arrays giving rise to the appearances and properties of organic compounds we usually observe. Obviously, the electrical, optical or magnetic properties of solid organic materials that are important requirements for future technologies and high-tech applications, as well as the stability and solubility behavior of a medicament depend on the structure of the molecule and the intramolecular forces, but even more decisively on the intermolecular forces, i. e. the packing structure of the molecules to which a general approach is lacking. This situation concerned ]. Maddox some years ago to such a degree that he described it as "one of the continuing scandals in the physical sciences" [see (1998) Nature 335:201; see also Ball, P. (1996) Nature 381:648]. The problem of predicting organic solid and crystal structures is very dif- cult.
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Contenuti
Directional Aspects of Intermolecular Interactions.- Supramolecular Synthons and Pattern Recognition.- Hydrogen-Bonded Ribbons, Tapes and Sheets as Motifs for Crystal Engineering.- Functional Organic Zeolite Analogues.- Crystalline Polymorphism of Organic Compounds.
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Design of Organic Solids. [= Topics in Current Chemistry 198].
Da: Antiquariat Braun, Gengenbach, Germania
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Orig. Hardcover. Condizione: Gut. 24 x 16 cm. 220 pp. *"The lively interest in organic solids stems from our increasing ability to manipulate and tune the properties of organic and organometallic materials (e.g. nonlinear behavior or electrical conductivity) by systematic variations of the molecular components. New insight derived from modern supramolecular chemistry are also allowing molecular level control of solid-state structure with the arrangement of functional molecular components into a defined solid architecture. Examples include the creation of nanoporous host lattices containing functional guest molecules and of defined nanomaterials. In this book, leading experts in the field give a state-of the art overview of our current knowledge and of future prospects, with chapters on directional aspects of intermolecular interactions, supramolecular synthon approaches, hydrogen-bonded tape, ribbon and sheet motifs, designed organic zeolite analogues, and crystalline polymorphism." (publisher). - Title with released firm stamp, else in very good unused condition. ISBN 9783540646457 Sprache: Englisch Gewicht in Gramm: 800. Codice articolo 136871
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Hardcover. Condizione: Near Fine. No Jacket. 3540646450. Hardcover, from closed pharmaceutical company library. English text. 230 pages, Author index for Volumes 151-198, illustrated with charts, tables and diagrams. Sections: Directional Aspects of Intermolecular Interactions; Supramolecular Synthons and Pattern Recognition; Hydrogen-Bonded Ribbons, Tapes and Sheets as Motifs for Crystal Engineering; Functional Organic Zeolite Analogues; Crystalline Polymorphism of Organic Compounds. Contents unread, as new, clean, tight and bright. Book. Codice articolo 030328
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