Assembled Lanthanide Complexes with Advanced Photophysical Properties

Yuichi Hirai

ISBN 10: 9811342776 / ISBN 13: 9789811342776

Editore: Springer, Springer, 2019

Riguardo questo articolo

Druck auf Anfrage Neuware - Printed after ordering - This thesis provides essential information on the systematic design of assembled lanthanide complexes for functional luminescent materials. It discusses the relationships between assembled structures and photo, thermal, and mechanical properties on the basis of crystallography, spectroscopy, and thermodynamics. The described guidelines for assembled structures will be extremely valuable, both for industrial applications and for readers' fundamental understanding of solid-state photophysics and materials chemistry. Luminescent lanthanide complexes are promising candidates for lighting devices, lasers, and bio-probes owing to their line-like and long-lived emission arising from characteristic 4f-4f transitions. Low-vibrational and asymmetrical coordination structures around lanthanide ions have been introduced to achieve strong luminescence, using specific organic ligands. Recently, assembled lanthanide complexes including coordination polymers and metal organic frameworks have increasingly attracted attention as a new class of luminescent materials offering thermal stability and color tunability. However, improving the luminescence efficiencies of these compounds remains a challenge, and specific molecular designs to control assembled structures and yield additional physical properties have not been established. The author provides a group of bent-angled bridging ligands to boost photoluminescence efficiency, and successfully introduces for the first time glass formability and strong triboluminescence properties.

Codice articolo 9789811342776

Dati bibliografici

• Titolo: Assembled Lanthanide Complexes with Advanced Photophysical Properties
• Editore: Springer, Springer
• Data di pubblicazione: 2019
• Lingua: Inglese
• ISBN 10: 9811342776
• ISBN 13: 9789811342776
• Rilegatura: Taschenbuch
• Condizione: Neu
• Dimensioni: 235 L x 155 A x 8 P (millimetri) 235 millimetri di larghezza per 155 millimetri di altezza per 8 millimetri di profondità
• Peso: 201 grammi

Descrizione articolo

Riassunto

Nominated by Hokkaido University as an outstanding Ph.D. thesis

Facilitates the reader's understanding by explaining the details of how to synthesize and measure assembled lanthanide complexes

Provides detailed information about microscopy and computation that that has not been published previously

Dalla quarta di copertina

This thesis provides essential information on the systematic design of assembled lanthanide complexes for functional luminescent materials. It discusses the relationships between assembled structures and photo, thermal, and mechanical properties on the basis of crystallography, spectroscopy, and thermodynamics. The described guidelines for assembled structures will be extremely valuable, both for industrial applications and for readers’ fundamental understanding of solid-state photophysics and materials chemistry.

Luminescent lanthanide complexes are promising candidates for lighting devices, lasers, and bio-probes owing to their line-like and long-lived emission arising from characteristic 4f–4f transitions. Low-vibrational and asymmetrical coordination structures around lanthanide ions have been introduced to achieve strong luminescence, using specific organic ligands. Recently, assembled lanthanide complexes including coordination polymers and metal organic frameworks have increasingly attracted attention as a new class of luminescent materials offering thermal stability and color tunability. However, improving the luminescence efficiencies of these compounds remains a challenge, and specific molecular designs to control assembled structures and yield additional physical properties have not been established. The author provides a group of bent-angled bridging ligands to boost photoluminescence efficiency, and successfully introduces for the first time glass formability and strong triboluminescence properties.