Controlled/Living Radical Polymerization: Progress in ATRP, NMP and RAFT (Dhhs Publication)

ISBN 10: 0841237077 / ISBN 13: 9780841237070

Editore: American Chemical Society, 2000

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Riassunto:

This book examines recent progress in controlled/living radical polymerization. The volume focuses on three synthetic methods: atom transfer radical polymerization, nitroxide mediated polymerization and degenerative transfer via addition fragmentation. In addition, the volume covers the preparation and characterization of many never before seen materials using ATRP, NMP and RAFT.

Contenuti:

• ADVANCES IN CONVENTIONAL AND CONTROLLED RADICAL POLYMERIZATION
• 1: Classification and Comparison of Various Controlled/"Living" Radical Polymerizations
• 2: Kinetics of Controlled Radical Polymerization
• 3: Initiation and Termination Rates of Free-Radical Polymerizations Carried Out Within Extended Ranges of Temperature and Pressure
• 4: Stereochemistry in Radical Polymerization of Vinyl Esters
• 5: EPR Study of Conventional and Controlled Radical Polymerization
• 6: Models for Free Radical Copolymerization Kinetics
• 7: Topochemical Polymerization of 1-Naphthylmethylammonium Muconate and Sorate as the (E,E)-Diene Monomers in the Crystalline State
• NITROXIDE MEDIATED POLYMERIZATION
• 8: Use of Phosphonylated Nitroxides and Alkoxyamines in Controlled/"Living" Radical Polymerization
• 9: Progress Towards a Universal Initiator for Niroxide Mediated "Living" Free Radical Procedures
• 10: Nitroxide-Mediated Controlled Free-Radical Eclusion Polymerization of Styrene
• 11: Triazolinyl Radicals -an Alternative Radical with a New Mechanism in Controlled Radical Polymerization
• ATOM TRANSFER RADICAL POLYMERIZATION
• 12: Living Radical Polymerization of Styrene: RuCI2(PPh3)3 and Alkyl Iodide-based Initiating Systems1
• 13: Copper Mediated Living Radical Polymerization Utilising Biological and End Group Modified Poly(ethylene-co-butylene) Macroinitiators
• 14: Atom Transfer Radical (Co)polymeriazation of Styrene and Butyl Acrylate
• 15: The Copper Catalyst in Atom Transfer Radical Polymerizations - Structural Observations
• 16: Atom Transfer Radical Polymerization of Vinyl Monomers Mediated by Stable Ruthenium-Carbene Complexes
• 17: Polychloraoalkanes as ATRP Initiators. Application to the Synthesis of Block Copolymers from the Combination of Conventional Radical Polymerization and ATRP
• 18: Controlled Radical Polymerizations Utilizing Preformed Metal Complexes Based on Substituted Bipyridines and Terpyridines
• 19: Reverse Atom Transfer Radical Polymerization Using AIBN or BPO as Initiator
• OTHER METHODS FOR CONTROLLED RADICAL POLYMERIZATION
• 20: Synthesis of Defined Polymers by Reversible Addition-Fragmentation Chain Transfer (The Raft Process)
• 21: Preparation of Macromonomers via Chain Transfer - With and Without Added Chain Transfer Agent
• 22: Endgroup Control in Catlytic Chain Transfer Polymerization
• NEW MATERIALS BY CONTROLLED RADICAL POLYMERIZATION
• 23: Stars and Star-Block Copolymers of Precise Functionality by Atom Transfer Radical Polymerization
• 24: Controlled/"Living" Radical Polymerization: The Next Frontier in Polymer Science
• 25: Copolymerization of N-Butyl Acrylate with Methyl Methacrylate and PMMA Macromonomers: Comparison of Reactivity Ratios in Conventional and Atom Transfer Radical Copolymerization
• 26: Qyantitative Derivatizations of 1-Choloro-1Phenylethyl Chain End of Polysteyrene Obtained by Quasiliving Atom Transfer Radical Polymerization
• 27: Synthesis of Alternating Copolymers of N-Substituted Maleimides with Tyrene via Atom Transfer Radical Polymerization
• 28: Controlled Radical Polymerization of Styrene and Arcylnoitrile
• 29: SYnthesis of Oligomers by Stable Free Radical Polymerization of Acrylated, Methacrylates, and Styrene with Alkozyamin Initiators
• 30: Potential Impact of Controlled Radical Polymerization on Markets for Polymeric Materials

Dati bibliografici

Titolo: Controlled/Living Radical Polymerization: ...
Casa editrice: American Chemical Society
Data di pubblicazione: 2000
Legatura: Hardcover
Condizione: Like New
Tipologia articolo: book