Laboratory Manual for Organic Chemistry: A Microscale Approach. Questo articolo non è disponibile.Laboratory Manual for Organic Chemistry: A Microscale Approach

This laboratory manual for organic chemistry courses provides an investigative approach for doing hands-on experimental work. It has been class-tested and fine-tuned for six years. It comprises largely non-traditional experiments that are designed to be covered in one three-hour laboratory period.

1 Safety in the Laboratory

2 Introduction

3 Melting Points

4 Crystallization

5 Distillation

6 Gas Chromatography

7 Thin-Layer Chromatography

8 Extraction: Separation of an Unknown Mixture

9 An Introuction to Stereochemistry: Use of Molecular Models

10 Infared Spectroscopy

11 Nuclear Magnetic Resonance Spectroscopy

12 Assignment of Structure by IR and 1H-NMR Spectroscopy

13 Preparative Scale GLC. Separation of Carvone and Limonene from Caroway Seed Oil

14 SN1 and SN2 Reactions

15 E2 Elimination Reactions, Dehydrobromination of the Byutyl Bromides, C4H9Br

16 Elimination Reaction, Dehydration of Butyl Alcohols

17 Hydroboration-Oxidation of Alkenes

18 Reduction of Ketones to Alcohols with Sodium Borohydride

19 Stereospecific Bromination of cis- and trans-Stilbene

20 Diphenylacetylene and (E)-1,2-Dibromostilbene

21 Addition Polymerization

22 The Diels-Alder Reaction

23 Aromatic Substitution I: Bromination of Aniline, Acetanilide, and Phenol

24 Aromatic Substitution II: Nitration of Methyl Benzoate: Relative Reactivity of Aromatic Compounds: A Competitive Nitration

25 The Grignard Reaction: The Synthesis of Triphenylmethanol

26 Chromic Acid Oxidation of Para-Nitrotoluene to Para-Nitrobenzoic Acid

27 Oxidation of Alcohols by a Chromate-Impregnated Resin: Following a Reaction by TLC

28 The Haloform Reaction. Oxidation of Aryl Methyl Ketones to Aromatic Carboxylic Acids

29 Synthesis of Isopentyl Acetate by Fischer Esterification

30 Acetylation: Aspirin and N-Acetylanthranilic Acid

31 Preparation of a Liquid Crystal: The Enol Acetate of 4-Cholestene-3-one

32 The Claisen-Schmidt Reaction: Benzalacetone and Dibenzalacetone

33 Aryldiazonium Ion Reactions: Formation, Displacement, Coupling

34 Dyes Produced by Diazo Coupling and Diazo Imaging

35 Imaging Dyes in Color Photography

36 Qualitative Organic Analysis. Part 1: Preliminary Measurements and Classification Tests

37 Qualitative Organic Analysis. Part 2: Prepartion of Derivatives and Final Identification

38 Tables of Physical Properties of Compounds and their Derivatives

Appendix