Rapid Production of Micro- and Nano-particles Using Supercritical Water (Hardcover)

Zhen Fang

ISBN 10: 3642129862 / ISBN 13: 9783642129865

Editore: Springer-Verlag Berlin and Heidelberg GmbH & Co. KG, Berlin, 2010

Riguardo questo articolo

Hardcover. Thisbookistalkingabouthowtousesupercriticalwater(SCW)torapidlyproduce micro- and nano-particles of metal oxides, inorganic salts, metals and organics. Itcoversbasicprinciples,experimentalmethodologiesandreactors,particlep- duction,characterizationsandapplicationsaswellastherecentadvancement. Fine particlescanbeproducedbybothchemicalandphysicalprecipitationofproducts from SCW. They can be used as catalysts, materials in ceramics and electronic devices andcompositematerials. Particlesareeasilyproduced continuouslyina owreactorinshortreactiontimes(0. 4s?2min)butcanalsobesynthesizedin batchreactorsforlongreactiontimes(e. g. ,12h). Theycanbeeasilystudiedin-situ microscopically(optical/IR/Raman/SR-XRD)inanopticalmicro-reactor,diamond anvilcell. Thesize,sizedistribution,crystalgrowth&structure,andmorphologyof particlescanbecontrolledbychangingtheconcentrationsofstatingmaterials,pH, pressures,temperatures,heating&coolingrates,organicmodi cations,reducingor oxidizingatmospheres, owratesandreactiontimes. Thisisthe rstbooktosystematicallyintroduceusingSCWforproductionof neparticles. Itisanidealreferencebookforengineers,researchersandgraduate studentsinmaterialscienceandengineering. vii Acknowledgments I would like to thank Drs.T. Ogi & T. Minowa (Biomass Technology Research Center,NationalInstituteofAdvancedIndustrialScienceandTechnology,Japan), and Profs. K. Arai, H. Inomata, R. L. Smith Jr. and T. Adschiri (Chemical Engineering,TohokuUniversity,Japan),whoinitiallyintroducedthehydrothermal andsupercritical uidsareastomewhenIworkedinJapanfrom1996to1999. Thanks are also due to Profs. J. A. Kozinski, R. I. L. Guthrie (Materials Engineering,McGillUniversity,Canada)andI. S. Butler(Chemistry,McGill)for theirguidanceinmyworkonhydrothermalprocessduringmyworkinCanadafrom 1999to2007. Profs. W. Bassett (Geological Sciences, Cornell University) and D. Baker (Earth&PlanetarySciences,McGill)forinstructionsregardingDAC,Dr. I-Ming Chou(U. S. GeologicalSurvey)forusefuldiscussionsofthepressurecalculation procedure. Drs. M. Watanabe and T. Sato (Research Center of Supercritical Fluid Technology, Tohoku University, Japan) for discussions about the experimental set-upofthebatchand owreactors. Drs. S. Xu,H. Assaaoudi,R. HashaikehandA. Sobhy,whoworkedwithmeat McGillinCanada. ix Contents 1 Introduction.1 1. 1 Background .1 1. 2 RapidExpansionofSupercriticalSolution(RESS)Process .4 1.3 SupercriticalAntisolvent(SAS)Process .4 1. 4 OtherPhysicalProcesses .5 1. 5 SupercriticalWaterProcess .5 References.8 2 Supercritical Water Process.11 2. 1 Introduction .11 2. 2 BatchReactor .15 2. 3 FlowReactor.18 2. 4 DiamondAnvilCell(DAC).20 References.25 3 Metal Oxides Synthesis.29 3. 1 Introduction .29 3. 2 Boehmite(AlOOH) .30 3. 3 Ferrites.31 3. 4 Phosphor(YAG) .32 3. 5 LiCoO /LiMn O .33 2 2 4 3. 6 Ce Zr O (x =0?1).33 1?x x 2 3. 7 PotassiumHexatitanate,PotassiumNiobateandTitania .35 3. 8 ZincOxide.38 3. 9 Nickel,Nickel/CobaltOxide. This book details progress in use of supercritical water (SCW) to synthesize nano- and micro- oxides, inorganic salts and metal particles, and shows how polymer/biomass particles can be produced by the precipitation of solutes from SCW. Shipping may be from multiple locations in the US or from the UK, depending on stock availability.

Codice articolo 9783642129865

Dati bibliografici

• Titolo: Rapid Production of Micro- and Nano-particles Using Supercritical Water (Hardcover)
• Editore: Springer-Verlag Berlin and Heidelberg GmbH & Co. KG, Berlin
• Data di pubblicazione: 2010
• Lingua: Inglese
• ISBN 10: 3642129862
• ISBN 13: 9783642129865
• Rilegatura: Hardcover
• Condizione: new

Descrizione articolo

Riassunto

Profs. W. Bassett (Geological Sciences, Cornell University) and D. Baker (Earth&PlanetarySciences,McGill)forinstructionsregardingDAC,Dr. I-Ming Chou(U. S. GeologicalSurvey)forusefuldiscussionsofthepressurecalculation procedure. Drs. M. Watanabe and T. Sato (Research Center of Supercritical Fluid Technology, Tohoku University, Japan) for discussions about the experimental set-upofthebatchand owreactors. Drs. S. Xu,H. Assaaoudi,R. HashaikehandA. Sobhy,whoworkedwithmeat McGillinCanada. ix Contents 1 Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1. 1 Background . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1. 2 RapidExpansionofSupercriticalSolution(RESS)Process . . . 4 1. 3 SupercriticalAntisolvent(SAS)Process . . . . . . . . . . . . . 4 1. 4 OtherPhysicalProcesses . . . . . . . . . . . . . . . . . . . . . 5 1. 5 SupercriticalWaterProcess . . . . . . . . . . . . . . . . . . . . 5 References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 2 Supercritical Water Process. . . . . . . . . . . . . . . . . . . . . . 11 2. 1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 2. 2 BatchReactor . . . . . . . . . . . . . . . . . . . . . . . . . . . 15 2. 3 FlowReactor. . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 2. 4 DiamondAnvilCell(DAC). . . . . . . . . . . . . . . . . . . . 20 References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25 3 Metal Oxides Synthesis. . . . . . . . . . . . . . . . . . . . . . . . . 29 3. 1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29 3. 2 Boehmite(AlOOH) . . . . . . . . . . . . . . . . . . . . . . . . 30 3. 3 Ferrites. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31 3. 4 Phosphor(YAG) . . . . . . . . . . . . . . . . . . . . . . . . . . 32 3. 5 LiCoO /LiMn O . . . . . . . . . . . . . . . . . . . . . . . . . 33 2 2 4 3. 6 Ce Zr O (x =0?1). . . . . . . . . . . . . . . . . . . . . . 33 1?x x 2 3. 7 PotassiumHexatitanate,PotassiumNiobateandTitania . . . . . 35 3. 8 ZincOxide. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38 3. 9 Nickel,Nickel/CobaltOxide. . . . . . . . . . . . . . . . . . . .

Dalla quarta di copertina

This book shows how to use supercritical water (SCW) to synthesize nano- andmicro- oxides, inorganic salts and metal particles and its recentadvancement. Also polymer/biomass particles can be produced by using themethod of precipitation of solutes from SCW. The particles can be used ascatalysts for biomass conversions, materials in ceramics & electronic devicesand composite materials. Particles are easily produced continuously ina flow reactor in short reaction times or synthesized in a batch reactor in long reaction times. Besides the synthesis process, the book also present studies of the properties of these materials. The size, size distribution, crystal growth & structure, and morphology of particles produced by supercritical water can be controlled by the feed concentrations, pH, pressures, temperatures, heating & cooling rates, organic modifications, reducing or oxidizing atmospheres, flow rates and reaction times.