Theory and Practice of Direct Methods in Crystallography

Lingua: inglese

Editore: Springer, Springer Okt 2011, 2011

1461329817 / 9781461329817

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This item is printed on demand - Print on Demand Titel. Neuware -Direct methods of crystal structure determination are usually associated with techniques in which phases for a set of structure factors are determined from the corresponding experimental amplitudes by probabilistic calcula tions. It is thus implied that such ab initio phase calculations do not require a knowledge of atomic positions, and this basis distinguishes direct methods from other techniques for structure determination. An acceptably wider interpretation of the term direct methods leads to other important applica tions involving, inter alia, the use of heavy atoms, resolution-limited phase data for large molecules, rotation functions, and Fourier series. These topics are discussed in the later chapters of this book. Although some earlier theoretical investigations were made by Harker and Kaspar, direct methods may be considered to have begun around the year 1950. Important landmarks in the development of the subject include the book by Hauptmann and Karle, The Centrosymmetric Crystal (1953), the definitive paper by Karle and Karle in Acta Crystallographica (1966), and the recent (1978) sophisticated program package MULTAN 78 produced mainly by Germain, Main, and Woolfson. Woolfson's book, Direct Methods in Crystallography, was published in 1961, but because of the rapid progress in direct methods, much of it soon became outmoded. It is interesting to note that direct methods nearly came into being many years earlier. Certainly the E2 relationship was used implicitly by Lonsdale in 1928 in determining the crystal structure of hexamethylbenzene.Springer-Verlag KG, Sachsenplatz 4-6, 1201 Wien 436 pp. Englisch.…

Codice articolo 9781461329817

Titolo
Theory and Practice of Direct Methods in Crystallography
Autore
M. F. C. Ladd
Editore
Springer, Springer Okt 2011
Anno di pubblicazione
2011
Condizione
Neu
Rilegatura
Taschenbuch
Lingua
inglese
ISBN 10
1461329817
ISBN 13
9781461329817
Peso dell'articolo
657 grammi
Dimensioni
235x155x24 mm

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