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Dati bibliografici

Titolo: Controlled/Living Radical Polymerization: Progress in ATRP, NMP and RAFT (ACS Symposium Series)
Editore: American Chemical Society
Data di pubblicazione: 2000
Lingua: Inglese
ISBN 10: 0841237077
ISBN 13: 9780841237070
Rilegatura: Hardcover
Edizione: 1st Edition
Condizione: As New

Descrizione articolo

Riassunto

This book examines recent progress in controlled/living radical polymerization. The volume focuses on three synthetic methods: atom transfer radical polymerization, nitroxide mediated polymerization and degenerative transfer via addition fragmentation. In addition, the volume covers the preparation and characterization of many never before seen materials using ATRP, NMP and RAFT.

Contenuti

ADVANCES IN CONVENTIONAL AND CONTROLLED RADICAL POLYMERIZATION
1: Classification and Comparison of Various Controlled/"Living" Radical Polymerizations
2: Kinetics of Controlled Radical Polymerization
3: Initiation and Termination Rates of Free-Radical Polymerizations Carried Out Within Extended Ranges of Temperature and Pressure
4: Stereochemistry in Radical Polymerization of Vinyl Esters
5: EPR Study of Conventional and Controlled Radical Polymerization
6: Models for Free Radical Copolymerization Kinetics
7: Topochemical Polymerization of 1-Naphthylmethylammonium Muconate and Sorate as the (E,E)-Diene Monomers in the Crystalline State
NITROXIDE MEDIATED POLYMERIZATION
8: Use of Phosphonylated Nitroxides and Alkoxyamines in Controlled/"Living" Radical Polymerization
9: Progress Towards a Universal Initiator for Niroxide Mediated "Living" Free Radical Procedures
10: Nitroxide-Mediated Controlled Free-Radical Eclusion Polymerization of Styrene
11: Triazolinyl Radicals -an Alternative Radical with a New Mechanism in Controlled Radical Polymerization
ATOM TRANSFER RADICAL POLYMERIZATION
12: Living Radical Polymerization of Styrene: RuCI2(PPh3)3 and Alkyl Iodide-based Initiating Systems1
13: Copper Mediated Living Radical Polymerization Utilising Biological and End Group Modified Poly(ethylene-co-butylene) Macroinitiators
14: Atom Transfer Radical (Co)polymeriazation of Styrene and Butyl Acrylate
15: The Copper Catalyst in Atom Transfer Radical Polymerizations - Structural Observations
16: Atom Transfer Radical Polymerization of Vinyl Monomers Mediated by Stable Ruthenium-Carbene Complexes
17: Polychloraoalkanes as ATRP Initiators. Application to the Synthesis of Block Copolymers from the Combination of Conventional Radical Polymerization and ATRP
18: Controlled Radical Polymerizations Utilizing Preformed Metal Complexes Based on Substituted Bipyridines and Terpyridines
19: Reverse Atom Transfer Radical Polymerization Using AIBN or BPO as Initiator
OTHER METHODS FOR CONTROLLED RADICAL POLYMERIZATION
20: Synthesis of Defined Polymers by Reversible Addition-Fragmentation Chain Transfer (The Raft Process)
21: Preparation of Macromonomers via Chain Transfer - With and Without Added Chain Transfer Agent
22: Endgroup Control in Catlytic Chain Transfer Polymerization
NEW MATERIALS BY CONTROLLED RADICAL POLYMERIZATION
23: Stars and Star-Block Copolymers of Precise Functionality by Atom Transfer Radical Polymerization
24: Controlled/"Living" Radical Polymerization: The Next Frontier in Polymer Science
25: Copolymerization of N-Butyl Acrylate with Methyl Methacrylate and PMMA Macromonomers: Comparison of Reactivity Ratios in Conventional and Atom Transfer Radical Copolymerization
26: Qyantitative Derivatizations of 1-Choloro-1Phenylethyl Chain End of Polysteyrene Obtained by Quasiliving Atom Transfer Radical Polymerization
27: Synthesis of Alternating Copolymers of N-Substituted Maleimides with Tyrene via Atom Transfer Radical Polymerization
28: Controlled Radical Polymerization of Styrene and Arcylnoitrile
29: SYnthesis of Oligomers by Stable Free Radical Polymerization of Acrylated, Methacrylates, and Styrene with Alkozyamin Initiators
30: Potential Impact of Controlled Radical Polymerization on Markets for Polymeric Materials

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