9783642099588 - three-dimensional free-radical polymerization: cross-linked and hyper-branched polymers di korolyov, gennady v. v.; mogilevich, michael (7 risultati)

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Taschenbuch. Condizione: Neu. Druck auf Anfrage Neuware - Printed after ordering - At present, three-dimensional free-radical polymerization (TFRP) is a special eld of radical polymerization. TFRP is characterized by speci c kinetic regularities and mechanisms of processes for the formation of cross-linked or hyper-branched po-…mers, and they are different from the kinetics and mechanism of classical radical polymerization. The fundamental studies of kinetics and mechanism of TFRP with formation of cross-linked polymers have been carried out in three stages. The rst stage lasted from 1960 until 1983, and the main mechanisms of TFRP of oligo(acrylates) were established during this stage [1 3]. Condensation telomerization, being a universal oligo(acrylate) synthesis procedure, allows us to vary certain molecular parameters, such as length and exibility of oligomeric blocks, number and type of reactive groups (methacrylic or acrylic groups), and chemical nature of atomic groups of an oligomeric block, which represent the centers of strong intermolecular interactions. For this reason, oligo(acrylates) were very convenient compounds for establi- ing the main kinetic regularities of TFRP and regularities of formation of polymer three-dimensional cross-linkedstructures,according totheso-calledmicrohetero- neous mechanism (G.V. Korolev, 1977), at the topological and morphological levels.

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Condizione: New. Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. First book on the subject comprising the research results of the last 40 yearsIncludes synthesis, mechanism and physico-mechanical properties, thus important for the specialist in new hightech areasThree-Dimensional…Free-Radical Polymeriza.

Lingua: Inglese
Editore: Springer Berlin Heidelberg, Springer Berlin Heidelberg Okt 2010, 2010
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Taschenbuch. Condizione: Neu. This item is printed on demand - Print on Demand Titel. Neuware -At present, three-dimensional free-radical polymerization (TFRP) is a special eld of radical polymerization. TFRP is characterized by speci c kinetic regularities and mechanisms of processes for the formation of cross-linked or hyper-b…ranched po- mers, and they are different from the kinetics and mechanism of classical radical polymerization. The fundamental studies of kinetics and mechanism of TFRP with formation of cross-linked polymers have been carried out in three stages. The rst stage lasted from 1960 until 1983, and the main mechanisms of TFRP of oligo(acrylates) were established during this stage [1¿3]. Condensation telomerization, being a universal oligo(acrylate) synthesis procedure, allows us to vary certain molecular parameters, such as length and exibility of oligomeric blocks, number and type of reactive groups (methacrylic or acrylic groups), and chemical nature of atomic groups of an oligomeric block, which represent the centers of strong intermolecular interactions. For this reason, oligo(acrylates) were very convenient compounds for establi- ing the main kinetic regularities of TFRP and regularities of formation of polymer three-dimensional cross-linkedstructures,according totheso-calledmicrohetero- neous mechanism (G.V. Korolev, 1977), at the topological and morphological levels.Springer Verlag GmbH, Tiergartenstr. 17, 69121 Heidelberg 288 pp. Englisch.

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Taschenbuch. Condizione: Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -At present, three-dimensional free-radical polymerization (TFRP) is a special eld of radical polymerization. TFRP is characterized by speci c kinetic regularities and mechanisms of processes for the formation of cross-linked or hyp…er-branched po- mers, and they are different from the kinetics and mechanism of classical radical polymerization. The fundamental studies of kinetics and mechanism of TFRP with formation of cross-linked polymers have been carried out in three stages. The rst stage lasted from 1960 until 1983, and the main mechanisms of TFRP of oligo(acrylates) were established during this stage [1 3]. Condensation telomerization, being a universal oligo(acrylate) synthesis procedure, allows us to vary certain molecular parameters, such as length and exibility of oligomeric blocks, number and type of reactive groups (methacrylic or acrylic groups), and chemical nature of atomic groups of an oligomeric block, which represent the centers of strong intermolecular interactions. For this reason, oligo(acrylates) were very convenient compounds for establi- ing the main kinetic regularities of TFRP and regularities of formation of polymer three-dimensional cross-linkedstructures,according totheso-calledmicrohetero- neous mechanism (G.V. Korolev, 1977), at the topological and morphological levels. 288 pp. Englisch.