ISBN: 9789027713285 - matrix isolation spectroscopy: proceedings of the nato advanced study institute: 76 (9 risultati)

Hardcover. Condizione: Good. Exlibray with usual stamps, stickers, etc. Cover worn. All text clean This book provides one of the earliest systematic treatments of matrix isolation spectroscopy, a technique that revolutionized the study of transient and reactive species. Barnes covers: Fundamentals of matrix isolation: trapping molecules in inert solid matrices at cryogenic temperatures. Spectroscopic techniques: infrared, UV-visible, and Raman spectroscopy applied to isolated species. Applications: studying free radicals, ions, and unstable intermediates. Experimental methods: cryogenic apparatus, sample preparation, and detection systems. Comparative analysis: contrasts matrix isolation with gas-phase and solution spectroscopy. Ideal For Physical chemists and spectroscopists studying transient molecular species. Graduate students in chemical physics and spectroscopy. Historians of science interested in the development of cryogenic spectroscopy. Collectors of Plenum Press scientific monographs. Why It Matters Scientific significance: Matrix isolation opened new frontiers in molecular spectroscopy. Historical context: Reflects late-1970s advances in cryogenic techniques. Technical depth: Includes detailed experimental setups and data. Scarcity: Original Plenum hardcovers are uncommon, especially outside institutional libraries.…

Hardcover. Condizione: Very Good. Condizione sovraccoperta: Good. First Edition. 605pp.

Condizione: As New. Unread book in perfect condition.

Condizione: New. In English.

Condizione: New.

Hardback. Condizione: New. 1981 ed.

Condizione: New.

Hardback. Condizione: New. 1981 ed.

Buch. Condizione: Neu. Neuware - The matrix isolation (MI) method has now been used for nearly thirty years. During this period it has been actively developed and the range of problems tackled greatly extended. Originally it was used for studies of transient species involv ing vibrational, electronic and ESR spectroscopy. Nowadays the study of transient species forms a comparatively small part of HI work since it has been amply demonstrated that very fruitful information can be obtained of the structure and interactions of stable molecules and their aggregates. In addition to the s~ectroscopic methods mentioned above the MI technique is nowadays a standard method in research based on vibrational relaxation, luminescence, Mossbauer, magnetic circular dichroism, pulsed NMR and photoelectron spectroscopy. The matrix isolation technique affords considerable advantages over more conventional methods in most applications of spectroscopy. Areas where the technique has been widely applied, or shows great potential, include: metal atom chemistry, and its relation to surface chemistry, high temperature inorganic species, transition metal complexes, interstellar species, free radicals and unstable molecules, conformational studies, molecular com plexes, and intermolecular forces. …