Riassunto
This handbook provides essential practical information for industrial and state control laboratories and others concerned with ensuring compliance with European Community Directive 90/128/EEC relating to plastic materials and articles intended to come into contact with foodstuffs. This book on the additives used in plastics for food contact can be seen as a companion to "Spectra for the Identification of Monomers in Food Packaging", published in 1993. The handbook begins with a chapter describing the legal framework and the implementation of the European legislation. There is a brief description of the Dutch fast method to test compliance with legislation using this handbook. Then, a collection of spectra is given for the identification of 100 of the most important additives used in plastic packaging and coatings. These additives were selected from Synoptic Document No 7 after extensive consultation with researchers in the field and with representatives from European industry. For every additive there is an entry in the handbook giving the structural formula, CAS and PM number and trivial name, together with information on physical characteristics, the food contact uses of the derived plastic materials. There is a brief description of the analytical approach for testing compliance with SML or QM limits and reference to the literature including European research projects. FT-IR, MS and 1H-NMR spectra are proved in standard format for each substance, and gas-chromatographic retention data are provided as a help in identification.
Contenuti
Acids, fatty (C14-C18), alkyl (C14-C18) ester.- Acrylic acid, 2-tert-butyl-6-(3-tert-butyl-2-hydroxy-5-methylbenzyl)-4-methylphenyl ester.- Adipic acid, bis(2-ethylhexyl) ester.- Adipic acid, dibutyl ester.- Alkyl (C10-C13)benzenesulphonic acid, sodium salt.- Alkyl (C10-C20)sulphonic acid, esters with phenols.- Azelaic acid, bis(2-ethylhexyl) ester.- Azelaic acid, bis(6-methylheptyl) ester.- 2,5-Bis(5-tert-butyl-2-benzoxazolyl)thiophene.- N,N?-Bis(3-3,5-di-tert-butyl-4-hydroxyphenyl) propionyl) hydrazide.- Bis(2,4-di-tert-butylphenyl)pentaerythritol diphosphite.- Bis(4-ethylbenzylidene) sorbitol.- N,N-Bis(2-hydroxyethyl)alkyl(C8-C18)amine.- N, N?-Bis(2-hydroxyethyl)lauramide.- 2,4-Bis(octylmercapto)-6-(4-hydroxy-3,5-di-tert-butyl-anilino)-1,3,5-triazine.- 2,4-Bis(octylthiomethyl)-6-methylphenol.- Bisphenol A.- tert-Butyl-4-hydroxyanisole.- Citric acid, triethyl ester.- Dibenzothiazyl disulphide.- 2,6-Di-tert-butyl-p-cresol.- 3,5-Di-tert-buty 1-4-hydroxybenzylphosphonic acid, monoethyl ester, calcium salt.- 2,4-Dihydroxybenzophenone.- 4,4?-Dihydroxybenzophenone.- Di-n-octyltin bis(2-ethylhexyl mercaptoacetate).- Di-n-octyltin bis(isooctyl mercaptoacetate).- N, N?-Diphenylthiourea.- Dodecylbenzenesulphonic acid.- Erucamide.- 2-Ethoxy-2?-ethyloxanilide.- Ethylbenzene.- N,N?-Ethylenebisstearamide.- Ethyleneglycol bis(3,3-bis(3-tert-butyl-4-hydroxyphenyl)butyrate).- 2-Ethylhexanoic acid.- Gallic acid, propyl ester.- Glycerol monooleate.- Glycerol monostearate.- Glycerol triacetate.- 1,6-Hexamethylene bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionamide).- 1,6-Hexamethylene bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate).- 4-Hydroxybenzoic acid, methyl ester.- 2-(2-Hydroxy-3,5-bis(l, l-dimethylbenzyl)phenyl) benzotriazole.- 2-(2-Hydroxy-3-tert-butyl-5-methylphenyl)-5-chlorobenzotriazole.- 1-(2-Hydroxyethyl-4-hydroxy-2,2,6,6-tetramethyl piperidine-succinic acid, dimethyl ester, copolymer.- 2-Hydroxy-4-methoxybenzophenone.- 2-(2-Hydroxy-5-methylphenyl)benzotriazole.- 2-Hydroxy-4-n-octyloxybenzophenone.- 2,2?-Methylenebis(4-ethyl-6-tert-butylphenol).- 2,2?-Methylenebis(4-methyl-6-tert-butylphenol).- 2,2?-Methylenebis(4-methyl-6-cyclohexylphenol).- Monochlorobenzene.- 1-Octadecanol.- Octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate.- Oleamide.- Hydrocarbon waxes, paraffin and microcrystalline (hydrogenated).- Pentaerytritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxy-phenyl)propionate).- 2-Phenylindole.- Phosphoric acid, diphenyl 2-ethylhexyl ester.- Phosphoric acid, tributoxyethyl ester.- Phosphoric acid, tributyl ester.- Phosphoric acid, triisobutyl ester.- Phosphoric acid, triphenyl ester.- Phosphoric acid, tris(2-ethylhexyl) ester.- Phosphorous acid, tris(2,4-di-tert-butylphenyl) ester.- Phosphorous acid, tri(nonyl-and/or dinonylphenyl) ester.- Phthalic acid, benzyl butyl ester.- Phthalic acid, bis(2-ethylhexyl) ester.- Phthalic acid, dibutyl ester.- Phthalic acid, dicyclohexyl ester.- Phthalic acid, diethyl ester.- Phthalic acid, diisobutyl ester.- Phthalic acid, diisodecyl ester.- Phthalic acid, diisononyl ester.- Phthalic acid, diisooctyl ester.- Phthalic acid, dimethyl ester.- Polydimethylsiloxane.- Polyethyleneglycol ether of tallow fatty alcohol.- Polyethylene propylene)glycol.- Polyolefins.- Poly[6-[(l, 1,3,3-tetramethylbutyl)amino]-l,3,5-triazine-2,4-diyl]-[(2,2,6,6-tertramethyl-4-piperidyl)imino]hexamethylene[(2,2,6,6-tetramethyl-4-piperidyl)imono].- Sebacic acid, bis(2-ethylhexyl) ester.- Sebacic acid, dibutyl ester.- Sorbitan monolaurate.- Sorbitan monooleate.- Sorbitan monostearate.- Stearamide.- Stearic acid, butyl ester.- Stearic acid, esters with pentaerytritol.- Stearoylbenzoylmethane.- Sulphosuccinic acid, bis(2-ethylhexyl) ester, sodium salt.- Tetrakis(2,4-di-tert-butylphenyl)-4,4?-biphenylylene diphosphonite.- 4,4?-Thiobis(6-tert-butyl-3-methylphenol).- Thiodiethanol bis(3-(3,5-di-tert-butyï-4-hydroxyphenyl) propionate).- Thiodipropionic acid, didodecyl ester.- Thiodipropionic acid, ditetradecyl ester.- Triethyl acetylcitrate.- Triethyleneglycol bis(3-(3-tert-butyl-4-hydroxy-5-methylphenyl) propionate).- 1,1,1-Trimethylolpropane.- 1,3,5-Trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxybenzyl)benzene.- 1,3,5-Tris(3,5-di-tert-butyl-4-hydroxybenzyl)-l,3,5-triazine-2,4,6(lH,3H,5H)-trione.- in CAS number order.- Polymer abbreviations.
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